The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Hydrogen halides / HBr / JPL-2010(2011)_298K_152-230nm(rec)

DATAFILE: HBr_JPL-2010(2011)_298K_152-230nm(rec).txt
NAME: hydrogen bromide
FORMULA: HBr
AUTHOR(YEAR): JPL-2010(2011)
T: 298K
λ: 152-230nm(rec)
BIBLIOGRAPHY: S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17", JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
COMMENTS: JPL-2010 recommendation, adopting the earlier recommendation of

S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :

The spectra of

C.F. Goodeve and A.W.C. Taylor, "The continuous absorption spectrum of hydrogen bromide," Proc. Roy. Soc. London A 152, 221-230 (1935); DOI: 10.1098/rspa.1935.0187,

J. Romand, "Absorption ultraviolette dans la région de Schumann. Étude de: ClH, BrH et IH gazeux," Ann. Phys. (Paris) 4, 529-590 (1949); DOI: 10.1051/anphys/194912040529,

B.J. Huebert and R.M. Martin, "Gas-phase far-ultraviolet absorption spectrum of hydrogen bromide and hydrogen iodide," J. Phys. Chem. 72, 3046-3048 (1968); DOI: 10.1021/j100854a071, and

J.B. Nee, M. Suto, and L.Cl Lee, "Quantitative spectroscopy study of HBr in the 105 - 235 nm region," J. Chem. Phys. 85, 4919-4924 (1986); DOI: 10.1063/1.451728,

have been normalized to the value σ = 2.21×10-18 cm2 molecule-1 at 184.9 nm, which is the mean of the values reported by

A.R. Ravishankara, P.H. Wine, and A.O. Langford, "Absolute rate constant for the reaction OH + HBr → H2O + Br," Chem. Phys. Lett. 63, 479-484 (1979); DOI: 10.1016/0009-2614(79)80694-6,

H. Okabe, "Photochemistry of acetylene at 1849 Å," J. Chem. Phys. 78, 1312-1317 (1983); DOI: 10.1063/1.444868, and

S.B. Barone, A.A. Turnipseed, T. Gierczak, and A. Ravishankara, "Quantum yields of H(2S) and CH3S(2E) from the photolysis of simple organosulfur compounds at 193, 222, and 248 nm," J. Phys. Chem. 98, 11969-11977 (1994); DOI: 10.1021/j100097a024;

the normalized spectra have then been averaged:

152-168 nm mean of Romand (1949) and Nee et al. (1986),

170-180 nm mean of Romand (1949), Huebert and Martin (1968), and Nee et al. (1986),

182-230 nm mean of Goodeve and Taylor (1935), Romand (1949), Huebert and Martin (1968), and Nee et al. (1986)

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